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01 March 2015 | PSV Eindhoven - Ajax | - | | - | 24 August 2014 | Ajax - PSV Eindhoven | - | | - | 19 January 2014 | Ajax - PSV Eindhoven | - | | - | 22 September 2013 | PSV Eindhoven - Ajax | - | | - | 14 March 2010 | Ajax - PSV Eindhoven | - | | - | 16 August 2009 | PSV Eindhoven - Ajax | - | | - | 19 April 2009 | PSV Eindhoven - Ajax | - | | - | 16 November 2008 | Ajax - PSV Eindhoven | - | | - | 19 March 2008 | PSV Eindhoven - Ajax | - | | 0 - 0 | 30 January 2008 | Ajax - PSV Eindhoven | PSV Eindhoven | | 0 - 2 | 11 August 2007 | Ajax - PSV Eindhoven | Ajax | Supercup | 1 - 0 | 18 March 2007 | PSV Eindhoven - Ajax | Ajax | | 1 - 5 | 12 November 2006 | Ajax - PSV Eindhoven | PSV Eindhoven | | 0 - 1 | 13 August 2006 | Ajax - PSV Eindhoven | Ajax | SuperCup | 3 - 1 | 07 May 2006 | Ajax - PSV Eindhoven | Ajax | Cup Final | 2 - 1 | 11 March 2006 | Ajax - PSV Eindhoven | - | Eredivisie | 0 - 0 | 23 October 2005 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 1 - 0 | 05 August 2005 | PSV Eindhoven - Ajax | Ajax | SuperCup | 1 - 2 | 20 March 2005 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 0 - 4 | 24 October 2004 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 2 - 0 | 08 February 2004 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 2 - 1 | '42 | Vennegoor of Hesselink, Jan | '51 | Sneijder, Wesley | '61 | Mitea, Nicolae |
| 26 October 2003 | PSV Eindhoven - Ajax | - | Eredvisie | 2 - 2 | 23 March 2003 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 2 - 0 | 15 December 2002 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 2 - 4 | 11 August 2002 | Ajax - PSV Eindhoven | Ajax | Super Cup | 3 - 1 | 10 April 2002 | Ajax - PSV Eindhoven | Ajax | Dutch Cup Semi-Final | 3 - 0 | 24 March 2002 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 25 November 2001 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 3 | 08 April 2001 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 0 - 1 | 29 October 2000 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 10 February 2000 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 0 | 15 December 1999 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 3 | 04 April 1999 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 1 | 15 November 1998 | Ajax - PSV Eindhoven | - | Eredivisie | 2 - 2 | 16 August 1998 | Ajax - PSV Eindhoven | PSV Eindhoven | Super Cup | 0 - 2 | 07 May 1998 | Ajax - PSV Eindhoven | Ajax | Dutch Cup Final | 5 - 0 | 15 February 1998 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 21 December 1997 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 3 - 4 | 13 April 1997 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 2 - 0 | 22 December 1996 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 0 - 2 | 18 August 1996 | Ajax - PSV Eindhoven | PSV Eindhoven | Super Cup | 0 - 3 | 08 April 1996 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 05 November 1995 | Ajax - PSV Eindhoven | - | Eredivisie | 1 - 1 | 22 January 1995 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 1 - 0 | 23 October 1994 | PSV Eindhoven - Ajax | Ajax | Eredivisie | 1 - 4 | 06 February 1994 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 1 | 05 September 1993 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 2 - 0 | 14 February 1993 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 2 - 1 | 06 September 1992 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 2 | 09 August 1992 | Ajax - PSV Eindhoven | Ajax | Friendly | 3 - 0 | 09 February 1992 | Ajax - PSV Eindhoven | Ajax | Dutch Cup 3rd Round | 2 - 1 | 19 January 1992 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 1 - 0 | 20 October 1991 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 2 | 07 April 1991 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 1 | 28 October 1990 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 3 - 1 | 14 March 1990 | PSV Eindhoven - Ajax | - | Dutch Cup Semi-Final | 2 - 2 | 18 February 1990 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 3 - 2 | 05 January 1990 | Ajax - PSV Eindhoven | Ajax | Friendly | 2 - 1 | 10 September 1989 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 2 - 0 | 19 March 1989 | PSV Eindhoven - Ajax | Ajax | Eredivisie | 1 - 4 | 09 October 1988 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 2 - 0 | 07 February 1988 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 0 - 1 | 30 August 1987 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 2 | 29 March 1987 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 1 - 0 | 31 August 1986 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 3 - 0 | 16 March 1986 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 28 August 1985 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 2 - 4 | 02 June 1985 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 0 | 19 March 1985 | PSV Eindhoven - Ajax | PSV Eindhoven | Dutch Cup 3rd Round (Replay) | 2 - 0 | 13 March 1985 | Ajax - PSV Eindhoven | - | Dutch Cup 3rd Round | 1 - 1 | 16 December 1984 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 4 | 21 April 1984 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 1 - 0 | 05 November 1983 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 1 - 0 | 13 April 1983 | PSV Eindhoven - Ajax | PSV Eindhoven | Dutch Cup Semi-Final | 2 - 0 | 30 March 1983 | Ajax - PSV Eindhoven | Ajax | Dutch Cup Semi-Final | 2 - 0 | 06 March 1983 | Ajax - PSV Eindhoven | - | Eredivisie | 3 - 3 | 09 October 1982 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 4 - 0 | 18 April 1982 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 3 - 0 | 05 May 1981 | Ajax - PSV Eindhoven | Ajax | Dutch Cup Semi-Final | 2 - 1 | 15 April 1981 | PSV Eindhoven - Ajax | - | Dutch Cup Semi-Final | 2 - 2 | 07 March 1981 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 1 | 14 September 1980 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 5 - 2 | 25 April 1980 | Ajax - PSV Eindhoven | - | Dutch Cup Semi-Final | 1 - 1 | 16 April 1980 | PSV Eindhoven - Ajax | Ajax | Dutch Cup Semi-Final | 1 - 2 | 12 April 1980 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 11 November 1979 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 4 - 1 | 17 March 1979 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 1 | 09 September 1978 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 2 - 0 | 23 April 1978 | PSV Eindhoven - Ajax | Ajax | Eredivisie | 2 - 3 | 04 December 1977 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 4 | 29 January 1977 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 1 | 01 October 1976 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 1 - 0 | 27 March 1976 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 1 - 2 | 20 October 1975 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 6 - 2 | 27 April 1975 | Ajax - PSV Eindhoven | PSV Eindhoven | Eredivisie | 2 - 4 | 15 December 1974 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 03 April 1974 | Ajax - PSV Eindhoven | PSV Eindhoven | Dutch Cup Semi-Final | 1 - 2 | 23 March 1974 | PSV Eindhoven - Ajax | PSV Eindhoven | Eredivisie | 3 - 1 | 20 October 1973 | Ajax - PSV Eindhoven | - | Eredivisie | 1 - 1 | 11 February 1973 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 3 - 1 | 02 September 1972 | PSV Eindhoven - Ajax | Ajax | Eredivisie | 0 - 3 | 12 March 1972 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 4 - 1 | 25 September 1971 | PSV Eindhoven - Ajax | - | Eredivisie | 1 - 1 | 18 April 1971 | PSV Eindhoven - Ajax | Ajax | Eredivisie | 0 - 3 | 30 October 1970 | Ajax - PSV Eindhoven | Ajax | Eredivisie | 1 - 0 | 27 March 1970 | PSV Eindhoven - Ajax | Ajax | Dutch Cup Final | 0 - 2 |
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